个人简况
代成义,男,中共党员,现为威尼斯9499登录入口教授、博士生导师。教学方面主要讲授本科生《化学反应工程》、《能源化学工艺学》,以及研究生《碳中和前沿技术》;在ACS Nano, Advanced Functional Materials, Chemical Engineering Journal等国际期刊发表SCI检索论文50余篇;获授权国际专利1件,国家发明专利20余件;主持国家级科研项目4项,省部级科研项目5项,企业合作项目2项;入选陕西省高层次人才引进计划;获辽宁省2018年度优秀博士论文;威尼斯9499登录入口2018年度科研奖,2019年度优秀教师等奖励。
邮箱:daicy@nwu.edu.cn
主要学习与工作经历
2021.10-至今,威尼斯9499登录入口,威尼斯9499登录入口,教授,博士生导师
2017/01-2021.9,威尼斯9499登录入口,威尼斯9499登录入口,副教授
2016/09-2017/01,威尼斯9499登录入口,威尼斯9499登录入口,讲师
2011/09-2016/09,大连理工大学,能源化工,工学博士
主要研究领域
(1)“金属-分子筛”多功能催化剂设计、合成及应用
(2)二氧化碳催化转化制高附加值化学品
(3)等离子体催化与电催化
主持项目
(1) 甲醇制芳烃高效催化转化关键问题研究,国家重点研发计划课题,2018.5-2021.4,450万;
(2) CO2定向转化高效催化剂的设计和开发,国家重点研发计划课题,2022.12-2026.11,221万;
(3) 用于合成气与萘直接烷基化新工艺的双功能催化剂设计合成与构-效关系研究,国家自然科学基金面上项目,2023.1-2026.12,54万;
(4) 用于合成气制芳烃的中空纳米沸石封装金属催化剂的设计、合成及催化机理研究,国家自然科学基金青年基金,2018.1-2020.12,25万;
(5) 纳米分子筛-双金属燃烧催化剂设计制备及燃烧性能研究,国防科技重点实验室基金,2022.6-2024.6,25万。
(6) 乙烷与苯一步法制乙苯技术,威尼斯9499登录入口-延长石油集团合作项目,2022.1- 2023.12,30万;
(7) 苯与合成气一步法制甲苯/二甲苯技术研究,威尼斯9499登录入口-延长石油集团合作项目,2020.1-2021.12,30万;
(8) 粘结性低阶洗中煤热解提质-煤焦气化过程关键技术研究,陕西省重点研发计划课题,2022.1-2024.12,10万;
(9) 金属-分子筛双功能催化剂用于合成气与苯烷基化制甲苯/二甲苯研究,煤炭高效利用与绿色化工国家重点实验室开放课题,2021.1-2022.12;
(10)“金属-碳@中空沸石”多功能有机-无机杂化材料的开发及其在C1催化转化中的应用研究,精细化工国家重点实验室开放课题,2016.12-2019.3;
(11) 二氧化碳加氢制芳烃双功能催化剂的设计、合成及构效关系研究,陕西省科技厅自然科学基础研究计划,2018.1-2019.12;
(12) 甲烷无氧芳构化催化剂的设计合成,陕西省教育厅研究项目,2017.6- 2018.12;
(13) 金属-沸石双功能催化剂用于二氧化碳加氢制芳烃研究,威尼斯9499登录入口紫藤计划,2019.1-2020.12;
(14) 碳一化学品洁净高效转化制芳烃的催化基础,威尼斯9499登录入口登峰计划,2019.1-2020.12。
主要科研成果
已发表论文
2023年度
(1) Runze Jin, Ke Ma, Zhongshun Chen, Zhongqiang Tang, Haobin Hu, Jiaofei Wang, Zhuangzhuang Zhang, Chengyi Dai*, Xiaoxun Ma*, Effect of CO2 on the catalytic performance of Zn/ZSM-5 towards the conversion of methanol to aromatics, Fuel, 2023, 332, 126247.
(2) Zhongqiang Tang, Siyuan Zhao, Xiao Zhao, Runze Jin, Jiaofei Wang, Zhuangzhuang Zhang, Haobin Hu, Xinwen Guo, Chengyi Dai*, Xiaoxun Ma*, “ZnAlCrOx&HZSM-5” bifunctional catalyst for one-step alkylation of naphthalene and syngas, Fuel, 2023, 332, 126093.
(3) Gaosheng Ren, Zhihui Su, Yu Tang, Weichen Du, Nan Xu, Chengyi Dai*, Xiaoxun Ma*, 4-Mercaptobenzoic acid-anchored ultrafine Ag nanoparticles for efficient CO2 electrochemical reduction, Applied Surface Science, 2023, 608, 155251.
(4) Yu Tang, Yi Cui, Gaosheng Ren, Ke Ma, Xiaoxun Ma, Chengyi Dai*, Chunshan Song*, One-step synthesis of methanol and hydrogen from methane and water using non-thermal plasma and Cu-Mordenite catalyst. Fuel Processing Technology, 2023, 244, 107722.
2022年度
(1) Wenfei Bi, Yu Tang, Xuemei Li, Chengyi Dai*, Chunshan Song, Xinwen Guo, Xiaoxun Ma. One-step direct conversion of methane to methanol with water in non-thermal plasma. Communications Chemistry, 2022, 5, 124.
(2) Gaosheng Ren, Tianfu Dai, Yu Tang, Zhihui Su, Nan Xu, Weichen Du, Chengyi Dai*, Xiaoxun Ma*, Preparation of hydrophobic three-dimensional hierarchical porous zinc oxide for the promotion of electrochemical CO2 reduction, Journal of CO2 Utilization, 2022, 65, 102256.
(3) Xiao Zhao, Xuan Shi, Zhongshun Chen, Long Xu, Chengyi Dai*, Yazhou Zhang, Xinwen Guo, Dongyuan Yang*, Xiaoxun Ma*. Efficient conversion of benzene and syngas to toluene and xylene over ZnO-ZrO2&H-ZSM-5 bifunctional catalysts, Chin. J. Chem. Eng. 2022, 45, 203-210.
(4) Yi Cui, Hui Yang, Chengyi Dai,* Pengju Ren,* Chunshan Song, and Xiaoxun Ma Coupling of LaFeO3−Plasma Catalysis and Cu+/Cu0 Electrocatalysis for Direct Ammonia Synthesis from Air, Industrial & Engineering Chemistry Research, 2022, 61, 4816-4823.
(5) Runze Jin, Haobin Hu, Jiaofei Wang, Zhuangzhuang Zhang, Chengyi Dai*, Xiaoxun Ma*,SAPO-34 and Zn/ZSM-5 synergistic catalysis of methanol to aromatics from light olefins,New J. Chem., 2022,46, 8443-8450.
(6) Runze Jin, Ke Ma, Shutao Xu, Yingxu Wei, Lijuan Song, Zhijun Li, Penghui Zhang, Yufeng Wang, Jiaofei Wang, Zhuangzhuang Zhang, Xiaoxun Ma,* Haobin Hu,* Chengyi Dai* and Xinwen Guo*, Effect of acid distribution and pore structure of ZSM-5 on catalytic performance, React. Chem. Eng., 2022,7, 2152-2162.
(7) 赵潇; 陈中顺; 唐忠强; 石轩; 代成义*; 马晓迅*. EDTA辅助制备高活性费托合成催化剂[J]. 化工进展, 2022,41,759-769.
(8) 毕文菲,代成义*,李雪梅,贺建勋,赵彬然,马晓迅*. 等离子体与Cu-Pd/S-1催化剂协同催化甲烷转化制低碳烯烃[J]. 化工进展,2022,41,227-236.
(9) 石轩;杨东元;胡浩斌;王焦飞;张壮壮;贺建勋;代成义*;马晓迅*. 苯与合成气在ZnAlCrOx&HZSM-5双功能催化剂上一步法制甲苯/二甲苯[J]. 化工进展,2022,41,247-259.
2021年度
(1) Xuemei Li, Yueyue Jiao, Yi Cui, Chengyi Dai*, Pengju Ren*, Chunshan Song, Xiaoxun Ma. Synergistic Catalysis of the Synthesis of Ammonia with Co-Based Catalysts and Plasma: From Nanoparticles to a Single Atom. ACS Applied Materials & Interfaces 2021, 13, 44, 52498-52507.
(2) Chengyi Dai*, Menghan Zhang, Xinwen Guo, Xiaoxun Ma*, Mesoporous composite Ni-C-N/SA for selective adsorption of methylene blue from water. Chemical Engineering Journal, 2021, 407, 127181.
(3) Chengyi Dai*, Xuemei Li, Menghan Zhang, Yi Cui, Binran Zhao, Xiaoxun Ma*. A silica-supported Ni-based catalyst prepared using TEPA for the plasma synthesis of ammonia. International Journal of Hydrogen Energy, 2021, 46, 2213-2224.
(4) Chengyi Dai*, Xiao Zhao, Borui Hu, Xinbao Zhang, Qunxing Luo, Xinwen Guo, Xiaoxun Ma*. Effect of EDTA-2Na modification on Fe-Co/Al2O3 for hydrogenation of carbon dioxide to lower olefins and gasoline. Journal of CO2 Utilization, 2021, 43, 101369.
2020年度
(1) Chengyi Dai*, Kang Du, Zhongshun Chen, Xinwen Guo, Xiaoxun Ma* Synergistic catalysis of multi-stage-pore-rich H-BZSM-5 and Zn-ZSM-5 for the production of aromatic hydrocarbons from methanol via lower olefins. Ind. Eng. Chem. Res. 2020, 59, 20693-20700.
(2) Chengyi Dai, Kang Du, Chunshan Song*, Xinwen Guo*. Recent progress in synthesis and application of zeolite-encapsulated metal catalysts. Adv Catal. 2020, 91-133.
(3) Chengyi Dai*, Xiao Zhao, Borui Hu, Jiaxing Zhang, Qing-Qing Hao, Huiyong Chen, Xinwen Guo, and Xiaoxun Ma*,Hydrogenation of CO2 to aromatics over Fe-K/alkaline Al2O3 and P/ZSM-5 tandem catalysts. Ind. Eng. Chem. Res. 2020, 59, 19194-19202.
(4) 代成义*,陈中顺,杜康,赵潇,时一鸣,陈星月,刘丹,马晓迅*. 甲醇制芳烃催化剂及相关工艺研究进展. 化工进展, 2020,39,5029-5041.
2019年度及以前
(1) Chengyi Dai, Anfeng Zhang, Chunshan Song*, Xinwen Guo*. Chapter Two -Advances in the synthesis and catalysis of solid and hollow zeolite-encapsulated metal catalysts. Adv. Catal., 2018, 63, 75-115.
(2) Chengyi Dai, Anfeng Zhang, Lei Luo, Xinbao Zhang, Min Liu, Junhu Wang, Xinwen Guo*, Chunshan Song*. Hollow zeolite-encapsulated Fe-Cu bimetallic catalysts for phenol degradation. Catal. Today, 2017, 335-343.
(3) Chengyi Dai, Anfeng Zhang, Junjie Li, Changhong Nie, Chunshan Song and Xinwen Guo*, Precise control of the sizes of zeolite B-ZSM-5 based on seed surface crystallization. RSC Adv. 2017, 7, 37915-37922.
(4) Chengyi Dai, Anfeng Zhang, Lin Gu, Chunshan Song*, Xinwen Guo*. Hollow alveolus-like nanovesicle assembly with metal-encapsulated hollow zeolite nanocrystals. ACS Nano, 2016, 10, 7401-7408.
(5) Chengyi Dai, Anfeng Zhang, Junjie Li, Fangyu Song, Chunshan Song*, Xinwen Guo*. Facile one-step synthesis of hierarchical porous carbon monoliths as superior catalytic support for CO2 hydrogenation. RSC Adv., 2016, 6, 10831-10836.
(6) Chengyi Dai, Anfeng Zhang, Min Liu, Xinwen Guo*, Chunshan Song*. Hollow ZSM-5 with silicon-rich surface, double shells and functionalized interior with metallic nanoparticles and carbon nanotubes. Adv. Funct. Mater., 2015, 25, 7479-7487.
(7) Chengyi Dai, Shaohua Zhang, Anfeng Zhang, Chunshan Song*, Chuan Shi*, Xinwen Guo*. Hollow Zeolite encapsulated Ni-Pt bimetals for sintering and coking resistant dry reforming of methane. J. Mater. Chem. A, 2015, 3, 16461-16468.
(8) Chengyi Dai, Xinmin Li, Anfeng Zhang, Chun Liu*, Chunshan Song, Xinwen Guo*. Pd and Pd-CuO nanoparticles in hollow silicalite-1 single crystals for enhancing selectivity and activity for the Suzuki-Miyaura reaction. RSC Adv., 2015, 5, 40297-40302.
(9) Chengyi Dai, Anfeng Zhang, Junjie Li, Keke Hou, Min Liu, Chunshan Song*, Xinwen Guo*. Synthesis of yolk–shell HPW@Hollow silicalite-1 for esterification reaction. Chem. Commun., 2014, 50, 4846-4848.
(10) Chengyi Dai, Anfeng Zhang, Lingling Li, Keke Hou, Fanshu Ding, Jie Li, Dengyou Mu, Chunshan Song*, Min Liu, Xinwen Guo*. Synthesis of hollow nanocubes and macroporous monoliths of silicalite-1 by alkaline treatment. Chem. Mater., 2013, 25, 4197-4205.
获授权国家发明专利
(1) 代成义; 赵潇; 石轩; 代天富; 杨东元; 一种催化合成气与苯制甲苯和二甲苯的催化剂及其制备方法, ZL202010028062.9.
(2) 代成义; 郭新闻; 张安峰; 刘民; 侯珂珂; 谷琳; 一种中空式ZSM-5纳米沸石的制备方法, ZL201110398881.3.
(3) 代成义; 赵潇; 胡柏睿; 代天富; 马晓迅; 毕文菲; 杜康; 一种合成气制汽油联产低碳烯烃的催化剂及其制备方法, ZL201910630636.7.
(4) 代成义; 杜康; 陈中顺; 陈星月; 时一鸣; 刘丹; 马晓迅; 一种对低碳烯烃具有较高选择性的催化剂及其制备方法, ZL201910785483.3.
(5) 代成义; 张梦寒; 毕文菲; 李雪梅; 选择性吸附亚甲基蓝的吸附剂及其制备方法和应用, ZL201910701736.4.
(6) 代成义; 李雪梅; 崔懿; 张梦寒; 毕文菲; 应用于利用等离子体技术合成氨气的反应中的催化剂及其制备方法, ZL201910701715.2.
(7) 代成义; 时一鸣; 杜康; 陈星月; 马晓迅; 一种纳米棒状ZSM-5分子筛的制备方法, ZL201910702966.2.
(8) 代成义; 毕文菲;李雪梅;张梦寒;一种低温等离子体-光耦合甲烷制甲醇的催化剂的制备方法及制备甲醇的方法,ZL202010968347.0
(9) 代成义; 黄肖杰; 石轩; 耿景龙; 苏志慧; 杨东元; 孙育滨; 高伟; 一种乙醇两步法制1 ,3-丁二烯的催化剂的制备方法,ZL202110904158 .1
(10) 代成义; 赵潇; 唐忠强; 金润泽; 任高升; 一种用于合成气与萘一步法制2-甲基萘/2 ,6-二甲基萘的催化剂的制备方法及应用,ZL202011639988 .8
(11) 代成义; 赵潇; 陈中顺; 崔懿; 唐玉; 一种用于合成气与联苯/4-甲基联苯一步法甲基化的催化剂的制备方法和应用,ZL202011638844 .0
指导研究生获奖学金情况
2022-2023学年一等奖学金:任高升,唐玉,唐忠强
2021年国家奖学金:陈中顺
2023年3月更新